Author Topic: Questions for Lestat: Lestat's Lab  (Read 2195 times)

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Offline Lestat

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Re: Questions for Lestat: Lestat's Lab
« Reply #30 on: August 15, 2016, 03:03:36 AM »
Seen some reasonably priced elemental tellurium on ebay.

BUT its in fine (200mesh) dust form. I want natural crystalline tellurium 'metal', of flawless gemstone quality. Because its for me, perhaps, along with selenium metal in some forms, one of the most beautiful of all elements, along with big rocks of iodine, that look metallic of their own accord.
Beyond the pale. Way, way beyond the pale.

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Offline renaeden

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Re: Questions for Lestat: Lestat's Lab
« Reply #31 on: August 15, 2016, 03:55:49 AM »
I've noticed that since my memory and related issues became severe, I've started constantly catching myself using the wrong spelling for words where two meanings and spellings but similar or identical pronunciations, and Switching homophones. E.g 'bowl' and 'bole' or 'time' and 'thyme' although for some reason it doesn't  affect abbreviations much, either with words or other abbreviations, such as I'd be unlikely to switch 'STAB' and 'TBAB' (sodium triacetoxyborohydride) for example.
What is the cause of your memory loss? I would love for my memory to be better. I don't know if my ADHD is to blame or something else. But I'm having a rough time at college because of it.
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Offline WolFish

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Re: Questions for Lestat: Lestat's Lab
« Reply #32 on: August 15, 2016, 05:03:42 PM »
I've noticed that since my memory and related issues became severe, I've started constantly catching myself using the wrong spelling for words where two meanings and spellings but similar or identical pronunciations, and Switching homophones. E.g 'bowl' and 'bole' or 'time' and 'thyme' although for some reason it doesn't  affect abbreviations much, either with words or other abbreviations, such as I'd be unlikely to switch 'STAB' and 'TBAB' (sodium triacetoxyborohydride) for example.
What is the cause of your memory loss? I would love for my memory to be better. I don't know if my ADHD is to blame or something else. But I'm having a rough time at college because of it.
mine gets worse with stressors like starting classes or illness.
i wish lestat were into nutritional supplements. i don't have time to do the kind of research i used to do. fish oil might help, as well as ashwaghanda or holy basil. both reduce stress and when i take them stimulants work better.

do you have accommodations? i am afraid to ask for them because i am taking classes where i teach and i could see this woman who seriously doesn't like me getting hold of the information and using it against me. that happened in the bad job i had years ago.
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Offline Lestat

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Re: Questions for Lestat: Lestat's Lab
« Reply #33 on: August 15, 2016, 10:37:41 PM »
We do not know, Ren m'ilady, not for certain 'we' being myself, my doctor (my regular, most longterm GP, who I have been under the care of for years)

Thing is there are multiple suspects, of which I do have certain ones viewed by myself in a much higher level of certainty than others, but there have been things happened to me that could have done things.

There has been a head (and rest of me) injury, after I, ahem....dropped off a bridge. I suddenly, in an area I wasn't terribly familiar with at the time, got chased by some thugs. Was not terribly far from this small bar, and then heard 'WOT WOT WOT NIGGER!', had my back turned, and being both white and of a pretty much ghosty paie white at that, I naturally assumed that given the shoutings content it was not, being aimed at ME of all people.

It was. And by the time I turned round, the fucking drunken hooligans, thugs, general pikey verminwhores and complete and utter faggotarded cretinous scrotumsucking inbred fucking trash. The kind of filth that needs to be nailed to a brick wall, covered in boiling oil and set on fire.  There were 5-6-7 of them or thereabouts. I had no chance whatsoever in a fair fight, and I did not put all that much trust in an unfair one. It was on a main road, so I could draw neither knife nor revolver nor light-to-medium gauss. After all I could not very well start spitting bullets on a well-travelled road. And damned if I trusted in being able to take that many down even if they were sloshed, and couldn't rely on their being very intoxicated and thusly unable to fight well. Too much uncertainty, so I ran for it. Which I'd sooner do than get into a bloodbath any day. I'd rather avoid confrontation than start or have to end one, IF I possess the ability in any given set of circumstances to do so, I will avoid the fight. If I am going to be hurt in any event and cannot get away, or am with someone I care for and they are in trouble I WILL fight and I will not back down. BUT I would sooner avoid it being necessary in the first place. I won't take shit, but I don't give it out without good reason either. I just won't be treated like dirt or assaulted, and I will NEVER run whilst another who cannot defend themselves successfully if they are in the shit,  is vulnerable. I'm not cowardly like that. But in this case it was me, myself and I. So I legged it, sprinted down the road and came to a fence. Or what I thought was one. Vaulted over it, only to find that in fact it was no fence but covering the side of a railway bridge. LONG drop, must have been EASILY 40 feet, maybe more. To this day I do not know how in the name'o'fuckety mc fucking fuckweasel I avoided snapping my neck, breaking my back or ending up with two broken legs. Hit the bottom, rolled and bounced down an embankment full of rocks, into a bunch of briars and thorn bushes and nettles. Then smacked into the railway tracks.

Coming down but not having hit the deck yet, I honestly thought I was going to die that day. Or at least break more bones than I care even to think about. Instead I ended up having to wriggle into (owch!) and crouch down in those thorns whilst those fucking pricks hunted for me, hooting and bellowing abuse etc. They stayed in the area for a long time, and seemed quite determined to find me, root me out of my uncomfortable little hidey hole. Lucky for me I guess that I was dressed from head to toe in camo gear and combat boots. No, not wearing camo paint, but dressed in camo pants and wearing a long coat thats ex army uniform, a guy who used to be in special forces but later took work as care staff in the asperger's (rather than my Kanner's one) school, he gave me his old coat, and his former beret too. Still have both. That coat is windproof, waterproof and in jungle-temperate color DPM. And it was late at night, all being dark, so I think even now, that it probably helped keep me in one piece, with regard not to the long drop and bone-jarring crunch at the bottom, helped keep me unseen, hunkered down in the blackberry thicket. And being somewhat tougher than most material, of a very dense and tight weave. A little noisy when moving against itself yes, but I kept myself pressed to the ground, hid for the time those fucking mindless gobshites kept on at me then somehow managed to claw my way back out of the thorns and briars and nettles, aching like you wouldn't believe.

Had been (over)using G at the time, not being anywhere near as old and experienced as I now am (actually I don't touch it at all now), I was young, naive and carefree, careLESS in some senses, got myself in a bit of a bind with it, and being short acting and unable to return home and redose, trying to taper myself off it, went into full blown withdrawal, which didn't help, MOST painful and horribly unpleasant.  Called for an ambulance, after managing to get back up the steep sloping embankment, largely by clawing myself up, dragging myself using trees. And aching like you wouldn't bloody believe possible.  I'd smacked my head around pretty good. Well good in the sense of 'thoroughly sodding well'

Had to stay overnight in hospital, blood pressure had gone through the roof and seizures, as well as feeling like I'd been tied in a knot, and hit repeatedly with a golf club with a bag of bricks tied to the end. Or deprived of the chance ever to see the sight of my stalker 'Heretic''s face again (which would be torture in and of itself, never again to see her nor hear her voice, for I love her like you just wouldn't believe possible for one person to adore another. She means more to me than life itself. The most beautiful, the most  loveliest, sweetest lady...literally beauty incarnate. I've only ever felt like I do about her, about two other people I've ever known. A girl named kassiane (who doesn't know that I love her, real cutie this lass, and smart, and clever, with a good soul, an all round good egg, thoughtful, kind to the deserving, and possessed of a wonderfully acidic, acerbic, hilariously twisted sense of humor, I feel pretty bad, because I lost my email address when I for a long time, was unable to get online at all and need to get in contact with her, as I said I'd help this lady with something. And whilst she doesn't know it, I actually miss her terribly, and..well...in the time I've known her, I fell for her, fell in love with her, every time I think about her funny, dark, acerbic and dead-on-target razortongued sense of humor, of her purtyful eyes, even of the wonderful eulogy she did for a murdered little autistic girl named Katie McCarron, that warms my heart, for she put heart and soul into it and the result was beautiful in the way that it honoured little Katie; and to boot, that acid-tongued aspect of Kassi, of hers, she put it to truly excellent use in slicing to shreds the murdering BITCH that hurt Katie McCarron, who tragically died because of  the video-nasty and utter, irredeemable abomination titled 'autism every day', was released by those filth autism squeaks, because her 'mother' believed in it and them and thence acted upon it, murdering her own daughter, who by any
accounts was not some suffering, broken little wreck, not less than human and never for a fraction of an attosecond deserving of what was done to her.

Even though for a long time the blog kassiane used to have, titled ''Rettdevil's rants'', she had to take it down, but to this day I remember the heartfelt eulogy to honor little Katie. And, not just that, but the effort she put into writing it. A woman who daeeeeeeeeeeeeeee  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Beyond the pale. Way, way beyond the pale.

Requiescat in pacem, Wolfish, beloved of Pyraxis.

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Re: Questions for Lestat: Lestat's Lab
« Reply #34 on: August 17, 2016, 04:29:53 AM »
^Oops, fall asleep on your keyboard?

I looked up interactions between medications I take and it seems dexamphetamine may be blocked by haloperidol and possibly lithium too. Wish my psych had noticed this!

WolFish, I may try fish oil. I hope to find one that doesn't taste fishy, heh.
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Re: Questions for Lestat: Lestat's Lab
« Reply #35 on: August 17, 2016, 05:03:53 AM »
^Oops, fall asleep on your keyboard?

I looked up interactions between medications I take and it seems dexamphetamine may be blocked by haloperidol and possibly lithium too. Wish my psych had noticed this!

WolFish, I may try fish oil. I hope to find one that doesn't taste fishy, heh.

  Over here you can buy fish oil in flavorless capsules.  I'll bet you can too.  :)
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Re: Questions for Lestat: Lestat's Lab
« Reply #36 on: August 17, 2016, 05:27:46 AM »
I am a regular at the chemist down the road, I shall ask them what they recommend.

Kayleigh used to have a huge jar of fish oil and I tried those. They were fine... until I burped. Ew.
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Re: Questions for Lestat: Lestat's Lab
« Reply #37 on: August 17, 2016, 06:31:39 AM »
Something like that, Ren. Something like that....

If you can, Ren, and you go for trying fish oil, I'd aim for one of the species lower down the food-chain. Avoid apex predator species, as these are the fish that have the highest quantity of organomercury derivatives, chiefly the uber-noxious methyl- and dimethylmercury. Aside from some toxins produced by pathogenic organisms (for example botulinum toxins, the tripartite toxin-complex produced by Bacillus anthracis, tetanus toxin, shigatoxin and the like) and a very few inorganic chemical nasties (E.g nickel carbonyl, phosgene, and a few of the really extreme carcinogens, plus highly active radioisotopes if internally intaken) there aren't all THAT many things quite so nasty as some of those small-molecule organomercurials.

They tend to undergo a process of biomagnification, whereby fish and other marine organisms containing small quantities get eaten by the next species up the foodchain, thereby accumulating more of them in the species up one step, assuming the Hg source is not just a chance addition to it's dinnerplate rather than a major dietary item, over a lifetime, the species one step up from the initial source eats a lot of whatever that initial source is, and accumulates its Hg content, as do fellows of the species. Which of course, is going to be food for something bigger. And the something bigger, whatever it may be, does much the same. As does the next bigger bully in the playground, and so on and so on, concentrating Hg with every step up the foodchain until one reaches the very top-apex predators such as shark, marlin, tuna (the larger kinds especially, and the largest specimens of the larger species the most for tuna, as with other fish), swordfish, all the big, fast, powerful predators at the very top of the ladder. These should only be eaten as a treat really, because they have the highest concentrations of mercury amongst those marine critters we eat.

Eaten as a treat because they taste fucking good, that is, not because they are full of Hg. Didn't we get our RDA of vitamin Hg in all those juicy autism-causing MMR jabs:autism: haha.
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Re: Questions for Lestat: Lestat's Lab
« Reply #38 on: August 17, 2016, 08:17:09 AM »
Oooohh.....goody. one of my reagent orders arrived today in the mail.

Could tell what it was (SOCl2) straight away, because of the hellaceous, satanic stench of sulfur dioxide that was emanating from the box, and when it was opened, it was like Old Scratch himself had farted in a jar and mailed it, as even though the bottle is tightly capped and then covered in a considerable number of layers of tightly-wrapped, thick synthetic rubber tape its still off-gassing enough to smell the SO2 and HCl that are produced as its released fumes hydrolyse  in the air. I can smell the stuff while it sits on the lounge coffee table.

Thionyl chloride (SOCl2) is a volatile liquid, often confused with another oxychloride of sulfur, SO2Cl2, sulfuryl chloride, although the properties are somewhat different. They both hydrolyse giving off lots of nasty sulfurous fumes and hydrogen chloride gas, in moist air and can react violently with water, where they hydrolyse quickly, certainly SOCl2, not so sure how quick SO2Cl2 does in water, I've not worked with it.

Uses (of thionyl chloride) include chlorinations, particularly of alcohols, of amines, and of phenols, as well as another rather nifty use, for dehydrating inorganic metal chloride salts, that one cannot do so using heat due to decomposition. The salt to be dehydrated (for instance AlCl3, or ferric chloride for another example in their hydrated forms) can be refluxed with SOCl2, either neat or in anhydrous solvent, preferably chloroform or dichloromethane (methylene chloride, carbon tet could be used also but I would consider that way, way too precious and scarce a resource to ever waste upon so trivial a purpose to even consider using CCl4 for, because these days due to its toxicity its more or less judged anathema in most commercial and research labs, so its very, very difficult to obtain for most citizen chemists, unless they make their own. I might be able to buy it from one of my suppliers, but only one. I'm currently attempting to persuade someone to sell me some who should be able to obtain some for themselves, because they are pretty much only starting out in chemistry, and there are almost no uses for it as a solvent that they could not use chloroform for, or dichlor, or maybe tetra. There ARE uses for it, as a reagent rather than solvent though that I have been wanting for a long time to obtain some carbon tet to employ it in. So I am hoping to persuade him to sell me the entire liter he could if I am lucky obtain. I'll give him fair price or fair reagents in trade for it though and not leave him under any false impressions either about its usefulness to him, purposes it could be employed for, or scarcity. My terms offered will be both honest and fair, but I DO want that liter of C-tet under any circumstances and at near any price. If I cannot obtain it from my eastern european supplier of things hard to get who requires no end-user declarations, no official accounts to be held, indeed the only things she does require are twofold. One is payment, the other is the place she is to send it. Which is exactly how I like to do business.  The only questions asked, being are do I have any special requirements for packaging, shipping, customs declarations wording etc. That is, if you can find it, a service to be treasured and a contact to be cultivated and treated well.

All the more so considering the lovely prices she gets me on her products. Quite a nice seeming lady actually, has always done well by me. Unfortunately she is away at the moment on holiday, so I had to look elsewhere and pay a bit more than I'd have done otherwise for my thionyl chloride. But I wanted it this week not next week, nor the week after that. But NOW. Paid my money, got my reagents. From latvia with love, hhaha:P

I won't be opening THIS one outside of a sealed glovebox full of dried inert gas, because the stench it gives off even through the sealed, taped-up bottle is pretty foul.
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Re: Questions for Lestat: Lestat's Lab
« Reply #39 on: August 18, 2016, 06:14:11 PM »
The lab-grade (red) phosphorus (unlike some citizen chemists, I do not use MBRP) arrived, I'd been eagerly anticipating that for days, tomorrow methinks, I both clean up some lead, by melting it and skimming off the layer of oxides that will when melted form a skin on the top, and heat some of the red phosphorus in an inert atmosphere (argon will fulfil this purpose nicely, I have a tank, part full, not sure how much is left as my regulator lacks a pressure gauge, so I may just buy a new tank in order to make sure that I do not run out of gas during the process) and distil it, during heating it will evaporate, turning to the pyrophoric white allotrope of phosphorus as it recondenses from the gaseous phase, and then it will be collected and added to some of the cleaned up molten lead, kept at molten temperature for at least  a 19 hours. I'll need to buy some concentrated nitric acid first though, and once it arrives, dissolve the lead away after allowing it to cool.

Going to try cooling the lead very, very very slowly. I'd like to try doing it over several weeks in the hope of producing the hoped-for Hittorf's metallic/metalloid violet phosphorus,  not in the form of a powder or small, shot-like crystals but one large one, as slow cooling is the usual means for successfully producing large single crystals of crystalline materials in general. I'm also going to first cast the phosphorus into a mould made from the lead in solid form, as a stick, pouring over more lead and then raising the whole thing to the melting point of Pb, so the willy pete is in the shape of the hoped for solid crystal before I make with the molten lead. That way I can, I hope, assuming all goes well, produce a nice large single crystal of violet phosphorus, to form the start of my framed element collection.

I need to get some suitable appearing hardwoods as well, to build the frame of the display case. Already have some long glass strips too for cutting to size to make the front panels of the case. Going to aim for a real well-done work of art, to be nailed up onto the wall of the lab as a display piece.
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Re: Questions for Lestat: Lestat's Lab
« Reply #40 on: August 20, 2016, 05:49:50 PM »
Current project-extraction of thiamine (vitamin B1) from single-component vitamin pills, trying using boiling acetone first.

Then, cleavage of the cleaned thiamine to thiazolethanol and some pyrimidine crap. Clean the thiazolethanol  and react w/ thionyl chloride and a base to suck up the formed HCl, to give chlormethiazole freebase, clean it/workup then ready for use. In my experience with it, it really is the cream of the crop, the best out of any sedative-hypnotic I have ever tried.
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Re: Questions for Lestat: Lestat's Lab
« Reply #41 on: September 10, 2016, 04:33:51 AM »
Filtering something at the Buchner, to remove suspended solid reagent, which is collected on the filter paper (brown material at the top above the white disk, which is a fine sintered glass frit, that in and of itself is intended for vacuum filtration purposes, although a filter paper is placed over the top to catch as much as possible, the glass frit itself is a bit of a pain in the arse to clean, although its doable, pulling water, alcohol, other solvents etc through under vacuum (the little barb that protrudes just underneath the curved bottom of the Buchner funnel is for the attachment of a hose, connected to the vacuum line, water aspirator, or other suction pump but preferably a powerful vacuum pump to pull everything through and dry the frit off of solvent for the next step if its really really persistent fine and tough shite of the kind that seems determined to hang on come what may.

That, would be either chromic acid (a solution of chromic anhydride or dichromate in concentrated sulfuric acid (95-98% sulfuric are the common grades that would be used) which works, being a strongly oxidizing, and viciously acidic mixture, but it does leave behind residues of chromium salts, burns off anything organic pretty damn efficiently but not perfect, and the chromium crap left behinds needs a further thorough washing.

Or there is the nuclear option. Piranha acid. This is a mixture of concentrated sulfuric acid and fairly concentrated hydrogen peroxide, in various proportions and strengths depending on the need and the habits of the chemist. Its called piranha acid, or piranha bath, otherwise known under the name 'Caro's acid'. Piranha bath comes from the fact of its being used in acid baths for thoroughly cleansing the last tiny minute traces of crap off things, and that it voraciously attacks even inorganic carbon deposits, oxidizing them right the way to gaseous CO2.

The caveat is its unstable, should never be stored, ever; and the glass to be treated with piranha acid (peroxymonosulfuric acid) absolutely, certainly must be sure to be pre-cleaned thoroughly indeed, and stripped of everything but the last most minute traces of organics. This is for final cleansing to pristine state. Because with almost all organics, it forms extremely sensitive primary high explosive organoperoxides that can detonate with great violence, and are very, very brisant (of explosions, detonating with an extremely violent, fast-travelling shockwave compared to most explosives. Brisance/(of the event) brisant, refers to the shattering effect of the shock front when it hits something. And organoperoxides in general are very much so. Especially those formed from ether(s), ketone peroxides such as triacetonetriperoxide, and of course, you don't want something vicious as all hades vomited forth upon earth going kablooey, and even less so whilst contained in a glass vessel, and not to mention in the midst of my set of expensive glassware:P

Especially, because glass fragments show up poorly on hospital X-rays, so the shrapnel would be difficult to spot and remove.  But cautiously employed, with care, it can be used safely and it DOES do a very thorough job indeed. There is nothing organic that I know of, save perhaps fluoropolymers like teflon that will survive it. Piranha indeed, stuff chews through anything that gets fed to it.  Never something to be stored though, as it can decompose dangerously. It is to be made, used, neutralized and either disposed of or the much safer persulfate salts, such as sodium or potassium persulfate can be stored safely and made good use of. It isn't as if the stuff comes out dirty with whatever it previously got used to clean off the glass, because whatever that may have been, its been burnt to a few wisps of gas by the time it comes to render safe the acid bath.

I shudder to even think, though, what a spill of permonosulfuric or peroxydisulfuric acid would do to somebody, to living flesh. I imagine if the peroxide was strong enough it might even ignite tissue on contact.

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Re: Questions for Lestat: Lestat's Lab
« Reply #42 on: September 10, 2016, 04:38:37 AM »
A couple of the reagent storage shelves.

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Re: Questions for Lestat: Lestat's Lab
« Reply #43 on: September 10, 2016, 12:18:30 PM »
Tools of the trade:



The little white vial isn't any standard equipment, rather, its a little pot of platinum dust,  that is due to be dissolved in concentrated, strong acid for preparation of Pt/C (platinum on activated carbon) or maybe either platinum black, colloidal platinum or perhaps Pt oxide, that I brought down from the lab with me when I went to get the formic acid, activated charcoal and PdCl2 (palladium (II) chloride for making some palladium-based catalyst(s, possibly) for an opioid project (although these precious metal catalysts can be filtered out, washed clean of reaction products, solvents and reagents used almost in any case, and reused many, many many times before they begin to lose catalytic activity, and even then the metal itself can still be saved up until there is a substantial enough quantity of spent catalyst in the rubbish container assigned to the specific precious metal, and then using processes appropriate as per the metal in question, stripped from substrate, cleaned and recycled and made into new catalyst, or even if its truly befouled if theres enough of it it could always be sold as metal scrap for applications outside the sphere of chemistry. Hell I wouldn't even bother stripping the metal from the substrate but just sell it on as jeweller's scrap, lol. Let them pay for the substrate too.

I've been naughty plenty of times before in the past when selling on copper pipe and lead. I'd fill the pipes with cement or rocks and gravel and dirt, scrap iron, whatever is heaviest and plentiful then seal it in, or in the case of lead, melt it closed, or just hammer it closed or batter it with a brick round the folded edges then sell it as it appeared to be to scrap merchants. Not one of them ever cottoned on to my tricks, and ended up paying me many times over what it was ACTUALLY worth. Melted down, they would only find a layer of lead and instead of more lead inside, a fuckton of iron nails, slabs of iron etc or just occasionally, cast big lots of Pb round house brick with the depressions in them filled in (with rocks and gravel, with some soil to prevent any rattling if shaken, lol you don't think I'd give them any more lead than I had to, when they could be paying me for DIRT do you? :P)

Yes, I know, I know, it was a bit naughty of me, but at the time I had The Bitch living here as my lodger, and money barely sufficient to feed one, let alone feed me AND sustain the lab, had to do that and feed another hungry mouth, plus a cat. Well, various cats, given that The Bitch seemed to have a propensity for stealing kittens.
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Re: Questions for Lestat: Lestat's Lab
« Reply #44 on: October 19, 2016, 03:40:34 PM »
i think my neighbor is smoking something. there is a bad smell like a burnt wax candle or plastic burning. over the weekend they masked something with incense, but today it is acrid and burning my throat. the air filter is helping a little and i opened the window. usually it's just pot smell coming up from there.

i figure of all people our resident chemist can tell me what it might me.
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